Fe-Mg order-disorder in tremolite-actinolite-ferro-actinolite at ambient and high temperature

University of Washington, Department of Geological Sciences, Seattle, WA, United States
Geophysical Laboratory, United States

The crystal structures and M-site populations of a series of unheated and heat-treated, near-binary members of the actinolite series were determined from single-crystal X-ray diffraction data. Small, systematic differences in crystal structure (mean and individual bond lengths, octahedral distortions, and Mg-Fe site preferences) between the actinolite and cummingtonite series are documented and rationalized in terms of the bond-valence model. Mg-Fe (super 2+) site preferences among the M1, M2, and M3 sites in the actinolite series are small. Between M1 and M3, site preference (Fe (super 2+) slightly in favor of M1) is independent of temperature. Mg is favored in M2 over M1 in unheated samples (less strongly than in cummingtonite-grunerite), but Fe (super 2+) and Mg are virtually disordered in samples re-equilibrated at 700 degrees C. Site preference between M2 and M3 and possibly also between M1 and M2 appears to undergo a reversal as a result of heat treatment, but consideration of all sources of error renders this conclusion a tentative one, although the observation could be explained in terms of a bond valence deficiency. The ratio of Fe (super 2+) /Mg atoms on M4 cannot be accurately determined, but refinements indicate that, like cummingtonite-grunerite, it is larger than on all other M sites. Expansion of the cell dimensions with an increase in Fe/Mg ratio follows a pattern similar to that of thermal expansion, and a and beta are influenced by cummingtonite-grunerite solid solution. The data are consistent with a cell volume of 942.8 Aa ³ (or molar volume of 2.8388 J/bar) for end-member ferroactinolite, a first approximation that assumes a reciprocal, quadrilateral Delta V of zero.

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