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American Mineralogist; June 1999; v. 84; no. 5-6; p. 922-928
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Linking structure and chemistry in the schorl-dravite series

Erich S. Bloodaxe, John M. Hughes, M. Darby Dyar, Edward S. Grew, and Charles V. Guidotti

Miami University, Department of Geology, Oxford, OH, United States

Nine tourmaline crystals for which major and minor element composition data are available have been examined by single-crystal X-ray structure refinement. The single crystals were then analyzed for major elements (by electron microprobe methods), Fe (super 3+) /Fe (super 2+) (by synchrotron micro X-ray absorption near-edge spectroscopy), B and Li (by secondary ion mass spectrometry), and bulk H content (by uranium extraction). Despite recent claims based on chemical analyses, structure analysis suggests that no B exists in tetrahedral coordination in these samples. Analysis of cation ordering between the Y and Z octahedral sites suggests that the occurrence of an Fe (super 2+) atom on a Y octahedral site may be locally associated with the absence of Mg at both of the neighboring Z sites, as substitutions of Fe (super 2+) on Y and Mg on Z require antithetic shifts of the O6 anion.

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