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American Mineralogist; September 1999; v. 84; no. 9; p. 1451-1455
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Tetrahedral boron in naturally occurring tourmaline

S. L. Tagg, Herman Cho, M. Darby Dyar, and Edward S. Grew

Pacific Northwest National Laboratory, Environmental Molecular Sciences Laboratory, Richland, WA, United States

Evidence for boron in both trigonal and tetrahedral coordination has been found in 11 B magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) spectra of natural, inclusion-free specimens of aluminum-rich lithian tourmaline from granitic pegmatites.

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