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American Mineralogist; July 2002; v. 87; no. 7; p. 1018-1023
© 2002 Mineralogical Society of America
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Letter

Characterization of a high-pressure phase of silica from the Martian meteorite Shergotty

Przemyslaw Dera*, Charles T. Prewitt, Nabil Z. Boctor and Russell J. Hemley

Geophysical Laboratory and Center for High Pressure Research, Carnegie Institution of Washington, 5251 Broad Branch Road, N.W., Washington, D.C. 20015, U.S.A.

Correspondence: * E-mail: pdera{at}gl.ciw.edu

Recently, there has been substantial interest in post-stishovite high-pressure polymorphs of SiO2, discovered as extraterrestrial minerals, or synthesized in the laboratory. Previous investigators reported the presence of "{alpha}-PbO2-like" and "baddeleyite-like" SiO2 in the Martian meteorite Shergotty, and also the synthesis of an {alpha}-PbO2-like phase at pressures of 60–80 GPa in a laser-heated diamond anvil cell. To provide definitive information about the nature of the natural "{alpha}-PbO2 phase," we recovered a small sample from the Shergotty meteorite, obtained powder X-ray diffraction patterns, and performed a Rietveld refinement of the structure. The resulting cell parameters and space group are a = 4.097(1) Å, b = 5.0462(9) Å, c = 4.4946(8) Å, and Pbcn. The structure refinement confirms that this sample does have the {alpha}-PbO2 structure.




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