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American Mineralogist; January 2004; v. 89; no. 1; p. 219-231
© 2004 Mineralogical Society of America
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Incomplete retention of radiation damage in zircon from Sri Lanka

Lutz Nasdala1,*, Peter W. Reiners2, John I. Garver3, Allen K. Kennedy4, Richard A. Stern5, Etienne Balan6 and Richard Wirth7

1 Institut für Geowissenschaften–Mineralogie, Johannes Gutenberg-Universität, D-55099 Mainz, Germany
2 Department of Geology and Geophysics, Yale University, New Haven, Connecticut 06520-8109, U.S.A.
3 Department of Geology, Union College, Schenectady, New York 12308-2311, U.S.A.
4 Department of Applied Physics, Curtin University of Technology, GPO Box U1987, Perth, Western Australia 6001, Australia
5 J.C. Roddick Ion Microprobe Laboratory, Geological Survey of Canada, Natural Resources Canada, Ottawa, Ontario, Canada K1A 0E8
6 Laboratoire de Minéralogie-Cristallographie, UMR CNRS 7590, Universités Paris VI and VII, IPGP, 75252 Paris Cedex 05, France
7 GeoForschungsZentrum Potsdam, D-14473 Potsdam, Germany

Correspondence: * E-mail: nasdala{at}uni-mainz.de

A suite of 18 zircon gemstones from placers in the Highland/Southwestern Complex, Sri Lanka, were subjected to a comprehensive study of their radiation damages and ages. The investigation included X-ray diffraction, Raman and PL spectroscopy, electron microprobe, PIXE and HRTEM analysis, as well as (U-Th)/He and SHRIMP U-Th-Pb age determinations. Zircon samples described in this study are virtually homogeneous. They cover the range from slightly metamict to nearly amorphous. Generally concordant U-Th-Pb ages averaging 555 ± 11 Ma were obtained. Late Ordovician zircon (U-Th)/He ages scattering around 443 ± 9 Ma correspond reasonably well with previously determined biotite Rb-Sr ages for rocks from the HSWC. Slightly to moderately metamict zircon has retained the radiogenic He whereas only strongly radiation-damaged zircon (calculated total fluences exceeding ~3.5 x 1018 {alpha}-events/g) has experienced significant He loss. When compared to unannealed zircon from other localities, Sri Lanka zircon is about half as metamict as would correspond to complete damage accumulation over a ~555 m.y. lasting self-irradiation period, suggesting significant annealing of the structural radiation damage. Insufficient consideration of this has often resulted in significant underestimation of radiation effects in zircon. We suggest to estimate "effective {alpha}-doses" for Sri Lanka zircon by multiplying total {alpha}-fluences, which were calculated using the zircon U-Th-Pb age, by a correction factor of 0.55. This conversion may be applied to literature data as well, because all gem-zircon samples from Sri Lanka (this work and previous studies) seem to reveal the same general trends of property changes depending on the radiation damage. The use of "effective {alpha}-doses" for Sri Lanka zircon contributes to more reliable quantitative estimates of radiation effects and makes possible direct comparison between natural and synthetic radiation-damaged zircon.




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