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Mg/Si ratios of aqueous fluids coexisting with forsterite and enstatite based on the phase relations in the Mg₂SiO₄-SiO₂-H₂O system

¹ Institute for Geothermal Sciences, Graduate School of Science, Kyoto University, Beppu 874-0903, Japan.
² Department of Environmental Sciences, Faculty of Science, Ibaraki University, Mito 310-8512, Japan
³ Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Road, NW, Washington, D.C. 20015, U.S.A.
⁴ Japan Synchrotron Radiation Research Institute, SPring-8, Mikazuki, Hyogo 679-5198, Japan
⁵ Department of Physical Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526, Japan
⁶ Institute for Frontier Research on Earth Evolution, Japan Agency for Marine-Earth Science and Technology, Natsushima, Yokosuka 237-0061, Japan

Correspondence: ^* E-mail: kawamoto{at}bep.vgs.kyoto-u.ac.jp

Direct observation of aqueous fluids coexisting with MgSiO₃ (enstatite) and/or Mg₂SiO₄ (forsterite) was performed at 0.5–5.8 GPa and 800–1000 °C with an externally heated diamond-anvil cell and synchrotron X-rays. At 1000 °C in the MgSiO₃ –H₂O system, forsterite crystallizes below 3 GPa but not above that pressure. At 1000 °C in the Mg₂SiO₄ –H₂O system, forsterite congruently dissolves into the aqueous fluids up to 5 GPa. These observations suggest that the aqueous fluids coexisting with enstatite and forsterite have Mg/Si < 1 below 3 GPa and 1 < Mg/Si < 2 above that pressure.

Comparison with the previous studies reporting Mg/Si ratios of the aqueous fluid coexisting with enstatite and forsterite indicates that the Mg/Si ratios change rapidly from SiO₂-rich to MgO-rich at around 3 GPa and 1000 °C. This change can be related to possible structural changes of liquid water under these conditions. The aqueous fluids coexisting with enstatite and forsterite do have Mg/Si ratios similar to those found in the partial melts of H₂O-saturated peridotite. Somewhere within the upper mantle, these two fluids unite to form a single regime and cannot be distinguished from each other.

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