Quick Search:    advanced search

GSW Home   GeoRef Home   My GSW Alerts   Contact GSW   About GSW   Journals List   Help

This Article Figures Only Full Text Full Text (PDF) Alert me when this article is cited Alert me if a correction is posted Citation Map Services Email this article to a friend Similar articles in this journal Alert me to new issues of the journal Download to citation manager Google Scholar Articles by Comodi, P. Articles by Merlini, M.

The high-pressure–high-temperature behavior of bassanite

¹ Dipartimento di Scienze della Terra, Università di Perugia, Piazza dell’Università, 06100 Perugia, Italy
² Bayerisches Geoinstitut, Universität Bayreuth, Universität Strasse 30, 95440 Bayreuth, Germany
³ European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, BP220, F-38043 Grenoble, France
⁴ Dipartimento di Scienze della Terra, Università di Milano, Via Botticelli 23, 20133 Milano, Italy

Correspondence: ^* E-mail: comodip{at}unipg.it

The pressure evolution of bassanite (CaSO₄·H₂O) was investigated by synchrotron X-ray powder diffraction along three isotherms: at room temperature up to 33 GPa, at 109 °C up to 22 GPa, and at 200 °C up to 12 GPa.

The room-temperature cell-volume data, from 0.001 to 33 GPa, were fitted to a third-order Birch-Murnaghan equation-of-state, and a bulk modulus K₀ = 86(7) GPa with K' = 2.5(3) was obtained. The axial compressibility values are β_a = 3.7(2), β_b = 3.6(1), and β_c = 2.8(1) GPa^–1 (x10^–3) showing a slightly anisotropic behavior, with the least compressible direction along c axis. The strain tensor analysis shows that the main deformation occurs in the (010) plane in a direction 18° from the a axis.

The bulk moduli for isotherms 109 and 200 °C, were obtained by fitting cell-volume data with a second-order Birch-Murnaghan equation-of-state, with K' fixed at 4, and were found to be K₁₀₉ = 79(4) GPa and K₂₀₀ = 63(7) GPa, respectively. The axial compressibility values for isotherm 109 °C are β_a = 2.4(1), β_b = 3.0(1), β_c = 2.5(1) (x10^–3) GPa^–1, and for isotherm 200 °C they are β_a = 3.5(3), β_b = 3.4(3), β_c= 2.6(4) (x10^–3) GPa^–1. These two bulk moduli and the 20 °C bulk modulus, K_0,20 = 69(8) recalculated to a second-order Birch-Murnaghan EoS to be consistent, as well as the axial compressibilities, are similar for the three isotherms indicating that the thermal effect on the bulk moduli is not significant up to 200 °C. The size variation of the pseudo-hexagonal channel with pressure and temperature indicates that the sulfate "host" lattice and the H₂O "guest" molecule in bassanite do not undergo strong change up to 33 GPa and 200 °C.

Key Words: Bassanite • Ca-sulfate • compressibility • high temperature • high pressure • X-ray diffraction