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American Mineralogist
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American Mineralogist; July; v. 94; no. 7; p. 921-925; DOI: 10.2138/am.2009.3123
© 2009 Mineralogical Society of America
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Fe-Mg partitioning between perovskite and ferropericlase in the lower mantle

Takeshi Sakai1,*, Eiji Ohtani2, Hidenori Terasaki2, Naoki Sawada2, Yusuke Kobayashi2, Masaaki Miyahara2, Masahiko Nishijima3, Naohisa Hirao4, Yasuo Ohishi4 and Takumi Kikegawa5

1 International Advanced Research and Education Organization, Tohoku University, Sendai 980-8578, Japan
2 Institute of Mineralogy, Petrology, and Economic Geology, Tohoku University, Sendai 980-8578, Japan
3 Institute for Material Research, Tohoku University, Sendai 980-8577, Japan
4 Japan Synchrotron Radiation Research Institute, Hyogo 679-5198, Japan
5 Photon Factory, High Energy Accelerator Research Organization, Tsukuba 305-0801, Japan

Correspondence: * E-mail: t-sakai{at}m.tains.tohoku.ac.jp

Fe-Mg partitioning between perovskite and ferropericlase in the MgO-FeO-SiO2 system has been studied up to about 100 GPa at around 2000 K using a laser-heated diamond anvil cell (LHDAC). The compositions of both phases were determined by using analytical transmission electron microscopy (ATEM) on the recovered samples. Present results reveal that the Fe-Mg apparent partition coefficient between perovskite and ferropericlase [KDPv/Fp = (XFePvXMgFp)/(XMgPvXFeFp)] decreases with increasing pressure for a constant FeO of the system, and it decreases with increasing FeO content of ferropericlase. The gradual decrease of KDPv/Fp with increasing pressure is consistent with the spin transition in ferropericlase occurring in the broad pressure range from 50 to 100 GPa at around 2000 K.

Key Words: Perovskite • ferropericlase • Fe-Mg partitioning • LHDAC • FIB




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[Abstract] [Full Text] [PDF]




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